安田 伸広(Nobuhiro Yasuda)

プロフィール
回折・散乱Iグループ 結晶構造物性チーム

研究員

メール: nyasuda@spring8.or.jp


研究・開発項目は「高輝度放射光を利用したミクロンサイズ以下の単結晶および粉末試料1粒からの結晶構造解析」とし、主に単結晶構造解析ビームラインBL02B1と高フラックスビームラインBL40XUにて実験を行っています。最近は、新規に導入された検出器を利用した微小試料の迅速測定技術の開発を進めています。ビームラインの利用者に対して放射光でなければ測定のできないような微小単結晶構造解析法を提供し、実験のサポートおよび共同研究を行っています。また、所内外で測定されたデータ解析についても相談を受け付け、利用者の構造解析レベルの向上に力を注いでいます。また、単結晶構造解析の他に、放射光のパルス性を利用した特殊な実験のための測定装置や測定ソフトウェアの開発も行っています。


キーワード

  • 単結晶X線構造解析
  • 微小結晶
  • マイクロビーム
研究成果

研究論文

  • Ultrafast X-ray study of multi-hole GDI injector sprays: Effects of nozzle hole length and number on initial spray formation.Seoksu Moona, Keisuke Komada, Kiyotaka Sato, Hideaki Yokohata, Yoshitaka Wada, Nobuhiro Yasuda.Experimental Thermal and Fluid Science 68 (2015) 68–81
  • Effects of f–f Interactions on the Single-Molecule Magnet Properties of Terbium(III)–Phthalocyaninato Quintuple-Decker Complexes.Yoji Horii, Keiichi Katoh, Nobuhiro Yasuda, Brian K. Breedlove, and Masahiro Yamashita.Inorg. Chem., 2015, 54 (7), pp 3297–3305
  • Carbonyl group coordination preferences in square-planar NiII and PdII complexes of pentadentate ligands by electron-withdrawing/donating substituents" Inorganica Chimica Acta.Jianlin Han, José Luis Aceña, Nobuhiro Yasuda, Hidehiro Uekusa, Taizo Ono, Vadim A. Soloshonok , Karel D. Klika.Inorganica Chimica Acta, 433(1), 3-12(2015).
  • Self-Assembly of nm-Size Boroxine Cages from Diboronic Acids.Ono, Kosuke; Johmoto, Kohei; Yasuda, Nobuhiro; Uekusa, Hidehiro; Fujii, Shintaro; Kiguchi, Manabu; Iwasawa, Nobuharu.J. Am. Chem. Soc., 2015, 137 (22), pp 7015–7018
  • Ultrathin Inorganic Molecular Nanowire based on Polyoxometalates.Zhenxin Zhang, Toru Murayama, Masahiro Sadakane, Hiroko Ariga, Nobuhiro Yasuda, Norihito Sakaguchi, Kiyotaka Asakura, and Wataru Ueda.Nature Comm., 6, 8731(2015)
  • Spatially resolved analysis of short-range structure perturbations in a plastically bent molecular crystal.Manas K. Panda, Soumyajit Ghosh, Nobuhiro Yasuda, Taro Moriwaki, Goutam Dev Mukherjee, C. Malla Reddy & Pance Naumov.Nature Chemistry, 7, 65-72(2015)
  • Direct observation of lattice symmetry breaking at the hidden-order transition in URu2Si2"Sho Tonegawa, Shigeru Kasahara, Tatsuo Fukuda, Kunihisa Sugimoto, Nobuhiro Yasuda, Yugo Tsuruhara, Daiki Watanabe, Yuta Mizukami, Yoshinori Haga, Tatsuma Matsuda, Etsuji Yamamoto, Yoshichika Onuki, Hiroaki Ikeda, Yuji Matsuda, and Takasada Shibauchi.Nature Comm., 5, 4188 (2014).
  • Structural Elucidation of the Neuraminidase Inhibitor Zanamivir (Relenza): Creeping and Diffusion for Polymorph Separation.Naba K. Nath, Nobuhiro Yasuda, Wael M. Rabeh, Subash Chandra Sahoo, and Pance Naumov Cryst. Growth Des., 14, 770-774(2014)
  • Tetrahedral Connection of ε-Keggin-type Polyoxometalates To Form an All-Inorganic Octahedral Molecular Sieve with an Intrinsic 3D Pore System.Zhenxin Zhang, Masahiro Sadakane, Toru Murayama, Shoko Izumi, Nobuhiro Yasuda, Norihito Sakaguchi, and Wataru Ueda.Inorg. Chem., 53, 903-911(2014)
  • Preparation of α1- and α2-isomers of mono-Ru-substituted Dawson-type phosphotungstates with a dmso ligand, [α1/α2-P2W17O61RuII(dmso)]8, from [α2-P2W17O61]10 with Ru reagents, and their redox studies.Ogo, Shuhei; Shimizu, Noriko; Nishiki, Kensuke; Yasuda, Nobuhiro; Mizuta, Tsutomu; Sano, Tsuneji; Sadakane, Masahiro.Inorg. Chem., 53(7), 3526-3539(2014).
  • The Source of “Fairy Rings”: 2-Azahypoxanthine and its Metabolite Found in a Novel Purine Metabolic Pathway in Plants.Jae-Hoon Choi, Toshiyuki Ohnishi,Yasuhiro Yamakawa, Shogo Takeda, Shuhei Sekiguchi, Waki Maruyama, Kimiko Yamashita, Tomohiro Suzuki, Akio Morita, Takashi Ikka, Reiko Motohashi, Yoshikazu Kiriiwa, Hiroyuki Tobina, Tatsuo Asai, Shinji Tokuyama, Hirofumi Hirai, Nobuhiro Yasuda, Keiichi Noguchi, Tomohiro Asakawa, Shimpei Sugiyama, Toshiyuki Kan, Hirokazu Kawagishi.Angew. Chem. Int. Ed., 53(6), 1552-1555 (2014)NatureのNews & Viewsに選ばれました。ACS, C&ENに紹介されました。
  • Procedure-dependent construction of two isomers of trimeric self-assembled boronic esters.Kosuke Ono, Ryo Aizawa, Taiki Yamano, Suguru Ito, Nobuhiro Yasuda, Kohei Johmoto, Hidehiro Uekusa and Nobuharu Iwasawa.Chem. Commun., 2014,50, 13683-13686
  • Multifunctional One-Dimensional Rhodium(I)-Semiquinonato Complex: Substituent Effects on Crystal Structures and Solid-State Properties.Minoru Mitsumi, Shoji Ohtake, Yuki Kakuno, Yuuki Komatsu, Yoshiki Ozawa, Koshiro Toriumi, Nobuhiro Yasuda, Nobuaki Azuma, and Yuji Miyazaki.Inorg. Chem., 2014, 53 (21), 11710-11720
  • Partial Charge Transfer in the Shortest Possible Metallofullerene Peapod, La@C82 ⊂[11]Cycloparaphenylene.Takahiro Iwamoto, Zdenek Slanina, Naomi Mizorogi, Jingdong Guo, Takeshi Akasaka, Shigeru Nagase, Hikaru Takaya, Nobuhiro Yasuda, Tatsuhisa Kato and Shigeru Yamago.Chem. Eur. J. 2014, 20, 14403-14409.
  • The elusive crystal structure of the neuraminidase inhibitor Tamiflu (oseltamivir phosphate): molecular details of action.Pance Naumov, Nobuhiro Yasuda, Wael M. Rabeh and Joel Bernstein.Chem. Commun., 2013,49, 1948-1950
  • Isolation of bioactive steroids from the mushroom Stropharia rugosoannulata and absolute configuration of strophasterol B.Wu, J., Kobori, H., Kawaide, M., Suzuki, S., Choi, J-H., Yasuda, N., Noguchi, K., Matsumoto, T., Hirai, H. and Kawagishi, H.Biosci. Biotechnol. Biochem., 77(8) (2013) 1779-1781
  • An unusual sterol from the mushroom Stropharia rugosoannulata.Wu, J., Suzuki, T., Choi, J-H., Yasuda, N., Noguchi, K., Hirai, H. and Kawagishi, H.Tetrahedron Lett., 54 (2013) 4900-4902
  • Armillariols A to C from the culture broth of Armillaria sp.Hajime Kobori, Atsushi Sekiya, Nobuhiro Yasuda, Keiichi Noguchi, Tomohiro Suzuki, Jae-Hoon Choi, Hirofumi Hirai, Hirokazu Kawagishi.Tetrahedron Lett., 54 (2013) 5481-5483
  • Synthesis and Self-Assembly of NCN-Pincer Pd-Complex-Bound Norvalines.Kazuki Ogata, Daisuke Sasano, Tomoya Yokoi, Ryota Yoshida, Toshio Takenaka, Katsuhiro Isozaki, Hirofumi Seike, Tetsuya Ogawa, Hiroki Kurata, Nobuhiro Yasuda, Hikaru Takaya and Masaharu Nakamura.Chem. Eur. J., 19(37), 12356-12375(2013).
  • PCP-Pincer Palladium Complex-Bound Norvalines: Synthesis, Self-Assembly Property, and Catalytic Activity toward 1,4-Addition of Arylboronic Acid.Hikaru Takaya, Takashi Iwaya, Kazuki Ogata, Katsuhiro Isozaki, Tomoya Yokoi, Ryota Yoshida, Nobuhiro Yasuda, Hirofumi Seike, Toshio Takenaka and Masaharu Nakamura.Synlett, 24(15), 1910-1914(2013).
  • System of laser pump and synchrotron radiation probe microdiffraction to investigate optical recording process.Nobuhiro Yasuda, Yoshimitsu Fukuyama, Shigeru Kimura, Kiminori Ito, Yoshihito Tanaka, Hitoshi Osawa, Toshiyuki Matsunaga, Rie Kojima, Kazuya Hisada, Akio Tsuchino, Masahiro Birukawa, Noboru Yamada, Koji Sekiguchi, Kazuhiko Fujiie, Osamu Kawakubo, and Masaki Takata.Rev. Sci. Instrum. 84, 063902 (2013)
  • Phase-Change Nanodot Material for an Optical Memory.Noboru Yamada, Rie Kojima, Kazuya Hisada, Takashi Mihara, Akio Tsuchino, Norihito Fujinoki, Masahiro Birukawa, Toshiyuki Matsunaga, Nobuhiro Yasuda, Yoshimitsu Fukuyama, Kiminori Ito, Yoshihito Tanaka, Shigeru Kimura and Masaki Takata.Advanced Optical Materials, 1(11), 820-826(2013).
  • Size- and Orientation-Selective Encapsulation of C70 by Cycloparaphenylenes.Takahiro Iwamoto, Yoshiki Watanabe, Hikaru Takaya, Takeharu Haino, Nobuhiro Yasuda, Shigeru Yamago.Chemistry - A European Journal, 19(42), 14061-14068(2013).
  • Synthesis and physical properties of a ball-like three-dimensional π-conjugated molecule.Eiichi Kayahara,Takahiro Iwamoto, Hikaru Takaya, Toshiyasu Suzuki, Mamoru Fujitsuka, Tetsuro Majima, Nobuhiro Yasuda, Naoto Matsuyama, Shu Seki & Shigeru Yamago.Nat. Commun. 2013, 4, 2694. プレスリリース
  • Isolation and Characterization of the Cycloparaphenylene Radical Cation and Dication.Eiichi Kayahara, Takahiko Kouyama, Tatsuhisa Kato, Hikaru Takaya, Nobuhiro Yasuda, Shigeru Yamago.Angew. Chem. Int. Ed., 52, 13722-13726. (2013) Science Editor's choiceに選ばれました
  • Anomalous Lattice Shrink of a Single CeO2 Submicrometer Particle in an Optical Trap.Yoshimitsu Fukuyama, Nobuhiro Yasuda, Shigeru Kimura, and Masaki Takata.J. Phys. Soc. Jpn., 82, 114608(2013).
  • Synthesis and Supramolecular Association of NCN-Pincer Pd-Complex-bound Norvaline Derivatives toward Fabrication of Controlled Metal Array.Kazuki Ogata, Daisuke Sasano, Tomoya Yokoi, Katsuhiro Isozaki, Hirofumi Seike, Nobuhiro Yasuda, Tetsuya Ogawa, Hiroki Kurata, Hikaru Takaya, and Masaharu Nakamura.Chem. Lett., 2012, 41 194-196.
  • Multiple-Decker Phthalocyaninato Dinuclear Lanthanoid(III) Single-Molecule Magnets with Dual-Magnetic Relaxation Processes.Keiichi Katoh, Yoji Horii, Nobuhiro Yasuda, Wolfgang Wernsdorfer, Koshiro Toriumi, Brian K. Breedlove and Masahiro Yamashita.Dalton Trans., 2012, 41, 13582-13600.  Hot Articleに選ばれました
  • Strophasterols A to D with an Unprecedented Steroid Skeleton: From the Mushroom Stropharia rugosoannulata.Jing Wu, Shinji Tokuyama, Kaoru Nagai, Nobuhiro Yasuda, Keiichi Noguchi, Tetsuo Matsumoto, Hirofumi Hirai, Hirokazu Kawagishi.Angew. Chem. Int. Ed., 51(43), 10820-10822 (2012)
  • Submicrometer Single Crystal Diffractometry for Highly Accurate Structure Determination.N. Yasuda, Y. Fukuyama, K. Toriumi, S. Kimura, and M. Takata.AIP Conference Proceedings vol. 1234, 147-150 (2010).
  • Y. Fukuyama, N. Yasuda, S. Kimura, Y. Tanaka, H. Osawa, J. Kim, H. Murayama, Y. Moritomo, K. Toriumi, H. Tanaka, and M. Takata.Pump-robe X-ray Diffraction Technique for Irreversible Phase Change Materials.AIP Conference Proceedings vol. 1234, 215-218 (2010).
  • Y. Tanaka, T. Ohshima, Y. Fukuyama, N. Yasuda, J. Kim, H. Osawa, S. Kimura, T. Togashi, T. Hara, H. Kamioka, Y. Moritomo, H. Tanaka, M. Takata, H. Sengoku, and E. Nonoshita.High-precision Time Delay Control with Continuous Phase Shifter for Pump-Probe Experiments Using Synchrotron Radiation Pulses.AIP Conference Proceedings vol. 1234, 951-954 (2010).
  • Yoshimitsu Fukuyama, Nobuhiro Yasuda, Hayato Kamioka, Jungeun Kim, Takayuki Shibata, Hitoshi Osawa, Takeshi Nakagawa, Haruno Murayama, Kenichi Kato, Yoshihito Tanaka, Shigeru Kimura, Takashi Ohshima, Hitoshi Tanaka, Masaki Takata, and Yutaka Moritomo.Simultaneous Measurements of Picosecond Lattice and Charge Dynamics in Co–Fe Cyanides.Appl. Phys. Express 3 (2010) 016601
  • X 線ピンポイント構造計測による粉末試料1 粒からの単結晶構造解析.安田伸広, 福山祥光, 金 廷恩, 木村 滋, 村山美乃.日本結晶学会誌,51,201-204(2009)
  • X-ray diffractometry for the structure determination of a submicron single powder grain.Nobuhiro Yasuda, Haruno Murayama, Yoshimitsu Fukuyama, Jungeun Kim, Shigeru Kimura, Koshiro Toriumi, Yoshihito Tanaka, Yutaka Moritomo, Yoshihiro Kuroiwa, Kenichi Kato, Hitoshi Tanaka and Masaki Takata.J. Synchrotron Rad. 16, 352-357 (2009)
  • Structure and Electronic Configuration of an Iron(II) Complex in a LIESST State: A Pump and Probe Method .Chou-Fu Sheu, Kowa Chen, Szu-Miao Chen, Yuh-Sheng Wen, Gene-Hsiang Lee, Jin-Ming Chen, Jyh-Fu Lee, Bing-Ming Cheng, Hwo-Shuenn Sheu, Nobuhiro Yasuda, Yoshiki Ozawa, Koshiro Toriumi, Yu Wang.Chem. Eur. J. 2009, 15, 2384 – 2393
  • Photoinduced dynamics of prussian blue type cyanide.Y. Moritomo, T. Nakagawa, Y. Fukuyama, N. Yasuda, H. Oosawa, J. E. Kim, H. Kamioka, K. Kato, Y. Tanaka, S. Kimura, F. Nakada, S. Ohkoshi, H. Tanaka and M. Takata.J. Phys.: Conf. Ser. 148 012028(2009)
  • Structure and the mechanism of rapid phase change in amorphous Ge2Sb2Te5.M. Takata, Y. Tanaka, K. Kato, F. Yoshida, Y. Fukuyama, N. Yasuda, S. Kohara,H. Osawa, T. Nakagawa, J. Kim, H. Murayama, S. Kimura, H. Kamioka, Y. Moritomo, T. Matsunaga, R. Kojima, N. Yamada, K. Toriumi, T. Ohshima & H. Tanaka.Phys. Chem. Glasses: Eur. J. Glass Sci. Technol. B, June 2009, 50 (3), 205–211
  • Development of Picosecond Time-Resolved Microbeam X-ray Diffraction Technique for Investigation of Optical Recording Process.Yoshihito Tanaka, Yoshimitsu Fukuyama, Nobuhiro Yasuda, Jungeun Kim, Haruno Murayama, Shinji Kohara, Hitoshi Osawa, Takeshi Nakagawa, Shigeru Kimura, Kenich Kato, Fumiko Yoshida, Hayato Kamioka, Yutaka Moritomo, Toshiyuki Matsunaga, Rie Kojima, Noboru Yamada, Koshiro Toriumi, Takashi Ohshima, Hitoshi Tanaka, and Masaki Takata.Jpn. J. Appl. Phys. 48 (2009) 03A001 (5 pages)
  • Time-Resolved Investigation of Nanosecond Crystal Growth in Rapid-Phase-Change Materials: Correlation with the Recording Speed of Digital Versatile Disc Media.Y. Fukuyama, N. Yasuda, J. E. Kim, H. Murayama, Y. Tanaka, S. Kimura, K. Kato, S. Kohara, Y. Moritomo, T. Matsunaga, R. Kojima, N. Yamada, H. Tanaka, T. Ohshima and M. Takata, Applied Physics Express, 1, 045001 (2008).
  • Ultra-high-precision time control system over any long time delay for laser pump and synchrotron x-ray probe experiment.Y. Fukuyama, N. Yasuda, J. E. Kim, H. Murayama, T. Ohshima, Y. Tanaka, S. Kimura, H. Kamioka, Y. Moritomo, K. Toriumi, H. Tanaka, K. Kato, T. Ishikawa and M. Takata.Rev. Sci. Instrum., 79, (2008), 045107.
  • X-ray Pinpoint Structural Measurement for Nanomaterials and Devices at BL40XU of the SPring-8.S. Kimura, Y. Moritomo, Y. Tanaka, H. Tanaka, K. Toriumi, K. Kato, N. Yasuda, Y. Fukuyama, J. Kim, H. Murayama and M. Takata.AIP Conference Proceedings vol. 879, 1238-1241 (2007).
  • Fluorophilicity and fluorophobicity in supramolecular assemblage.Ono, Taizo; Hayakawa, Yoshio; Uekusa, Hidehiro; Yasuda, Nobuhiro.Abstracts of Papers, 234th ACS National Meeting, Boston, MA, United States, August 19-23, 2007 (2007),
  • Isostructural Coordination Capsules for a Series of10 Different d5–d10 Transition-Metal Ions.Shuichi Hiraoka, Koji Harano, Motoo Shiro, Yoshiki Ozawa, Nobuhiro Yasuda, Koshiro Toriumi, and Mitsuhiko Shionoya.Angew. Chem. Int. Ed., 45(39) 6488-6491(2006)
  • Ab initio reconstruction of p-type icosahedral Zn–Mg–Ho quasicrystal structures.H. Takakura, A. Yamamoto, T. J. Sato, A. P. Tsai, Y. Ozawa, N. Yasuda, K. Toriumi Philosophical Magazine,Volume 86, Number 3-5 2006 621 – 627
  • Conclusive Determination of the Absolute Configuration of Chiral C60-Fullerene cis-3 Bisadducts by X-ray Crystallography and Circular Dichroism.Shunsuke Kuwahara, Kazuhiro Obata, Kazuhiro Yoshida, Takatoshi Matsumoto, Nobuyuki Harada, Nobuhiro Yasuda, Yoshiki Ozawa, Koshiro Toriumi.Angew. Chem. Int. Ed., 44(15) 2262-2265(2005)
  • A Hydro-Fluoro Hybrid Compound, Hermaphrodite, is Fluorophilic or Fluorophobic? A New Concept for the Fluorine-based Crystal Engineering.Hayakawa, Yoshio; Ono, Taizo; Yasuda, Nobuhiro; Uekusa, Hidehiro.Abstracts of Papers, 230th ACS National Meeting, Washington, DC, United States, Aug. 28-Sept. 1, 2005 (2005),FLUO-025.

著書

  • A Hydro-Fluoro Hybrid Compound, Hermaphrodite, Is Fluorophilic or Fluorophobic? A New Concept for the Fluorine-Based Crystal Engineering.T. Ono, H. Hayakawa,N. Yasuda,H. Uekusa,Y. Ohashi.Current Fluoroorganic Chemistry. New Synthetic Directions, Technologies, Materials and Biological Applications.ACS Symposium Series , Eds, V. A. Soloshonok, K. Mikami, T. Yamazaki, J. T. Welch, and J. Honek.Oxford University Press/ American Chemical Society: Washington DC, (2006).
  • 放射光を用いた単結晶X線構造解析のフロンティア:粉末1粒,複雑系分子,光誘起現象の構造解析.鳥海幸四郎、安田伸広.CSJ Current Review 14 放射光が拓く化学の現在と未来 pp.86-93.日本化学会 編 (2014)
  • 放射光による極微小単結晶構造解析.安田伸広.日本の結晶学(II)-その輝かしい発展- pp.191-192.日本結晶学会 (2014)

口頭発表

  • 放射光による単結晶X線構造解析の基礎.日本化学会第95春季年会(2015). 日本大学理工学部 船橋キャンパス
  • 放射光を利用した極微小単結晶構造解析の現状.第4回CSJ化学フェスタ(2014).タワーホール船堀
  • Diffraction Study of Long-period Stacking Ordered Phase Magnesium Alloys using Synchrotron Radiation.International Symposium on Long-Period Stacking Ordered Structure and Its Related Materials 2012 LPSO2012. Sapporo Convention Center(2012)
  • 放射光結晶化学研究における時分割測定と極微小結晶構造解析の将来展望.日本結晶学会年会(2010).大阪大学コンベンションセンター
  • 極微小単結晶を利用した精密構造解析.第23回日本放射光学会年会.イーグレひめじ(2010)
  • Nanometer-scale single crystal diffractometry for highly accurate structure determination.10th International Conference on Synchrotron Radiation and Instrumentation 2009 (SRI2009).Melbourne(2009)
  • 極微小単結晶領域構造解析のための放射光ピンポイント構造計測装置の現状.日本結晶学会年会(2007).東京工業大学(大岡山キャンパス)(2007)
  • 放射光マイクロビームによる極微小単結晶内での結晶相反応解析手法の開発.日本化学会第87春季年会(2007) 関西大学 千里山キャンパス
  • 反応現象のX線ピンポイント構造計測へむけて―ピンポイント構造計測装置の開発―.第20回日本放射光学会年会.広島国際会議場(2007)

競争的資金

  • 科研費:若手研究(B)(2006-2007年度).放射光X線による極微小単結晶X線構造解析法の開発
  • 科研費:若手研究(B)(2009-2010年度).ナノサイズ試料の1粒マニピュレーション技術の開発
  • 3. 科研費:新学術領域研究(研究領域提案型) (2012-2013年度).放射光マイクロビーム微小単結晶構造解析によるシンクロ型LPSO構造の原子配列解明

受賞歴

  • 本化学会第87春季年会(2007):優秀講演賞
  • LPSO2014:ポスター賞

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